Product ID:SZ-13, SZ13500
MSDS Date:10/15/1986
FSC:6850
NIIN:00N022027
MSDS Number: BLTNF

FISHER SCIENTIFIC

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Preparer: GASTON L PILLORI

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

WASH IMMED W/LARGE AMTS OF

RTECS: 9999999ZZ

EVIDENCE OF CHEM REMAINS (A MINIMUM OF 15 MIN). IN

RTECS: 9999999ZZ

IF

RTECS: 9999999ZZ

DO NOT INDUCE VOMITING. GIVE 1 OUNCE (30 ML) OF

RTECS: 9999999ZZ

IN CASE OF CHEM BURNS, COVER AREA

RTECS: 9999999ZZ

NITRIC ACID

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 6.5%

OSHA PEL 2 PPM; 4 PPM STEL

ACGIH TLV: 2 PPM; 4 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

0.7.

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 93.4%

ZINC OXIDE

CAS: 1314-13-2

RTECS: ZH4810000

Fraction By Weight: 0.1%

OSHA PEL 15MG/M3 TDUST/5 FUME

ACGIH TLV: 10MG/M3 TDUST; 9293

PERFORATION OF THE ESOPHAGUS & STOMACH

RTECS: 9999999ZZ

SEE ACUTE EXPOS.

RTECS: 9999999ZZ

REPEATED OR PROLONGED EXPOSURE MAY CAUSE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CORROSIVE. INHAL: 100PPM, ARE
IMMED DANGEROUS TO LIFE/HLTH. NO INHAL EFTS ARE ANTIC IN THE
PROPOSED(ANALYTICAL) USE OF THIS SOLN. SKIN: IMMED, SEV &
PENETRATING BURNS. EYE: DIRECT CONT W/ THE L IQ CAUSES PAIN,
PHOTOPHOBIA, TEARING, EDEMA, CORNEAL ULCERATION, SEV BURNS &
NECROSIS OF THE DEEPER TISS (EFTS OF OVEREX
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: W/PERM DMG. INGEST:IMMED PAIN IN THE
MOUTH, THROAT, & STOM MAY BE FOLLOWED BY NAUS, VOMIT, DIARR,
HEMATEMESIS, HEMOPTYSIS, HYPOTENSION, NEPHRITIS, ALBUMINURIA,
OLIGURIA, ANURIA, HEMATURIA, & POSS CIRCULATORY COLLAPSE. ASPHYXIA
FROM GLOTTAL EDEMA IS POSS. BURNS OF GI TRACT MAY BE SEV ENOUGH TO
CAUSE (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG
HAS STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY/BLOOD PRESS & ADMIN
OXYGEN IF AVAIL. KEEP WARM & AT REST. ADMIN OF OXYGEN SHLD BE
PERFORMED BY Q UALIFIED PERS. GET MED ATTN IMMED. SKIN: REMOVE
CONTAM CLTHG/ SHOES IMMED. WASH AFFECTED AREA W/SOAP OR MILD
DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (AT
LEAST 15 MIN). (ING 7)

Flash Point:WILL NOT BURN
Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY OR FOAM. FOR LARGER
FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:MOVE CONTRS FROM FIRE AREA IF POSS. COOL
CONTRS EXPOSED TO FLAMES W/WATER FROM SIDE UNTIL WELL AFTER FIRE IS
OUT. EXTINGUISH USING AGENTS INDICATED. (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE & EXPLOSION HAZARD WHEN
EXPOSED TO HEAT/FLAME. HOWEVER, CONTACT WITH COMMON METALS CAUSES
EVOLUTION OF FLAMMABLE GAS.

Spill Release Procedures:OCCUP SPILL: PROVIDE VENT. WEAR PERSONAL PROT
EQUIP. COVER W/SODA ASH. SCOOP UP & PLACE IN A SUITABLE CONTR.
CLOSE TIGHTLY & LABEL CORROSIVE. KEEP OUT OF SEWERS, WATERWAYS &
OTHER WATER SOURCES.
Neutralizing Agent:SEE SPILL/RELEASE PROCEDURES.

Handling and Storage Precautions:AVOID STORAGE WITH INCOMPATIBLE
MATERIALS.
Other Precautions:CORROSIVE. DO NOT WEAR CONTACT LENSES WHEN WORKING
WITH CHEMICALS.

Respiratory Protection:NONE REQUIRED IN THE PROPOSED (ANALYTICAL) USE
OF THIS SOLUTION. IF NEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:PROVIDE GENERAL DILUTION VENTILATION TO MEET PUBLISHED
EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:POLYETHYLENE, VITON & SARANEX PLASTICS.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:IMPERVIOUS CLTHG/EQUIP TO PVNT POSSIBILITY
OF SKIN CONT. EMER EYE-WASH & DELUGE SHOWER W/IN THE IMMED WORK
AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: AVOID SPLASHING/SPATTERING THIS MATL. IF LGE AMTS OF
COMBUST MATLS ARE INVOLVED, USE WATER SPRAY/FOG IN FLOODING AMTS.
USE WATER SPRAY TO ABSORB CORR VAPS. COOL CONTRS W/ FLOODING AMT S
OF WATER FROM AS FAR A DIST AS POSS. WEAR NIOSH/MSHA APPRVD
SCBA/FULL PROT EQUIP . CNDTNS(STAB):W/INCOMPAT MATLS

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:SEE ING 2
Vapor Density:SEE ING 2
Spec Gravity:1.1
pH:<0.01
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
SEE ORIGINAL MSDS.
Stability Condition to Avoid:AVOID HEATING TO THE BP, WHERE EMISSION OF
CORR MIST/VAP OCCURS. AVOID LEAKY/CORRODIBLE CONTRS. AVOID CONT
(SUPP DATA)
Hazardous Decomposition Products:ON BOILING, EMITS CORROSIVE MIST AND
NOX AS VAPORS.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.